The principle of detailed balance was explicitly introduced for collisions by Ludwig Boltzmann.
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Nevertheless, the principle of detailed balance is not necessary for entropy growth.
3.
In 1901, Rudolf Wegscheider introduced the principle of detailed balance for chemical kinetics.
4.
Lorentz stated that the principle of detailed balance is not applicable to collisions of polyatomic molecules.
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Thus, the principle of detailed balance is a sufficient but not necessary condition for entropy increase in Boltzmann kinetics.
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The principle of detailed balance says that in thermodynamic equilibrium every elementary process works equally in its forward and backward sense.
7.
Albert Einstein in 1916 used the principle of detailed balance in a background for his quantum theory of emission and absorption of radiation.
8.
Five years before Boltzmann, James Clerk Maxwell used the principle of detailed balance for gas kinetics with the reference to the principle of sufficient reason.
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Now, the principle of detailed balance is a standard part of the university courses in statistical mechanics, physical chemistry, chemical and physical kinetics.
10.
In 1981, Carlo Cercignani and Maria Lampis proved that the Lorentz arguments were wrong and the principle of detailed balance is valid for polyatomic molecules.
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